Blocking Three Escape Routes for Heat in a Flask
A good vacuum flask can keep soup hot through a long morning and keep water cold through a hot afternoon, but it does not make heat or cold. It only slows the trip that heat takes from a warm place to a cooler one. Heat is always on the move, and it has three different ways to travel, all of which a well-built flask manages to block.
The first way is conduction, in which heat passes from particle to particle through a solid or a liquid, like a message passed along a line of people. The second is convection, in which warmer fluid itself moves and carries heat with it, as when warm air rises from a heater. The third is radiation, in which heat travels as invisible waves that need no material to cross.
A flask is really two containers, one inside the other, joined only at the neck. Almost all the air has been pumped out of the gap between them, which leaves a vacuum, and because a vacuum has very few particles, heat has almost nothing to hand itself along, so conduction is stopped. With no air in the gap, there is also no moving air, so convection is stopped as well.
Radiation can still cross empty space, so the inner wall has a shiny, mirror-like coating. A shiny surface reflects heat waves back instead of letting them pass. The weak spot of a flask is its stopper, because heat can creep through the neck and the lid. That is why a flask loses heat slowly rather than never.