Why Chopping an Onion Brings Tears
Few kitchen jobs bring tears as quickly as chopping an onion. The onion is not sad, and neither is the cook. The tears come from a chemical defense that the plant developed over a very long time, probably to discourage animals from eating it.
Inside an intact onion, two kinds of substances are kept in separate compartments of its cells. One group is made of sulfur compounds. The other is a set of enzymes. While the onion is whole, they never meet. When a knife slices through the cells, the walls break and the contents mix. The enzymes quickly change the sulfur compounds into new ones, and one of them is a gas that drifts upward from the cutting board.
When the gas reaches your eyes, it dissolves in the thin layer of moisture covering them and forms a mild irritant. Nerves on the surface of the eye sense it and warn the brain. The brain answers by telling your tear glands to wash the irritant away. That is why your eyes water and sting.
Cooks have found a few ways to reduce the effect. A very sharp knife crushes fewer cells than a dull one, so less gas escapes. Chilling the onion in the refrigerator first slows the reactions. Cutting near a fan or an open window can blow the gas away from your face. Cooking the onion also ends the problem, because heat damages the enzymes.