Why Salad Dressing Separates in the Bottle
Shake a bottle of oil and vinegar dressing and it looks like one cloudy liquid. Set it on the shelf for a few minutes, and a golden layer of oil rises to the top while the watery vinegar sinks below. Why won't they stay mixed?
Vinegar is mostly water. Water molecules attract one another strongly, and they do not attract oil molecules nearly as much, so each liquid prefers to stay with its own kind. Oil is also less dense than water, which means a cup of oil weighs less than a cup of water. So when the droplets drift together, the oil floats to the top.
Shaking breaks the oil into tiny droplets scattered through the vinegar. This kind of mixture is called an emulsion, but a plain one is only temporary. The droplets bump together, join into bigger ones, and the layers form again.
Cooks have a fix. Adding a spoonful of mustard or a little egg yolk helps keep the mixture together. These foods contain substances called emulsifiers. Each emulsifier molecule is attracted to oil at one end and to water at the other, so it sits around the droplets like a coat and keeps them from merging. Mayonnaise is a famous example. It is made of oil and a bit of vinegar or lemon juice, held together by egg yolk, and it stays smooth in the refrigerator.