Why Frozen Seawater Is Not Very Salty
If you freeze a glass of salty water, the ice that forms is less salty than the water it came from. The same thing happens in the cold polar oceans. Sea ice is made of frozen seawater, yet it holds much less salt than the sea beneath it.
The reason lies in how ice crystals grow. As water freezes, its molecules lock into a neat pattern, and salt does not fit well into that pattern. Most of the salt is pushed out and stays in the liquid water nearby. Some of it is trapped in tiny pockets of very salty water, called brine, inside the ice. Salt also lowers the temperature at which water freezes, so seawater must get a little colder than fresh water before it turns to ice.
The salt that is pushed out has a big effect. Water with extra salt is heavier, so the cold, salty water sinks below the new ice. This sinking helps to stir the ocean and carry water from the surface toward the deep.
Sea ice also changes as it grows older. Over time the pockets of brine can drain through narrow channels and drip back into the sea. Ice that has survived for years can be fresh enough that explorers have melted it for drinking water, while ice that has just formed is still too salty to drink.